Metallopolymers with transition metals in the side-chain by living and controlled polymerization techniques

Metallopolymers with transition metals in the side-chain by living and controlled polymerization techniques

Work on side-chain transition metal-containing polymers prepared by controlled and living polymerizations is summarized, including living anionic polymerization (LAP), ring-opening metathesis polymerization (ROMP) and controlled radical polymerization (CRP) such as atom transfer radical polymerizati...

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Veröffentlicht in:Progress in polymer science 2014-10, Vol.39 (10), p.1742-1796
Hauptverfasser: Hardy, Christopher G., Zhang, Jiuyang, Yan, Yi, Ren, Lixia, Tang, Chuanbing
Format: Artikel
Sprache:eng
Schlagworte:
Addition polymerization
Anionic polymerization
Chain transfer
Controlled/living polymerization
Metal carbonyls
Metallocene
Metallopolymer
Organometallic
Polymerization
Radicals
Rafts
Transition metals
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Zusammenfassung:Work on side-chain transition metal-containing polymers prepared by controlled and living polymerizations is summarized, including living anionic polymerization (LAP), ring-opening metathesis polymerization (ROMP) and controlled radical polymerization (CRP) such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer polymerization (RAFT), and nitroxide-mediated polymerization (NMP). These polymers include metallocene-containing polymers, ferrocenylsilane polymers with additional metal at the side chain, metal carbonyl complex polymers, and ligated metal complex polymers.
ISSN:0079-6700
1873-1619
DOI:10.1016/j.progpolymsci.2014.03.002