Regional distribution of halogenated organophosphate flame retardants in seawater samples from three coastal cities in China

•We discussed halogenated OPFRs in seawater from the Yellow and East China Seas.•The Yellow Sea area around Lianyungang was more heavily polluted than East China Sea.•Halogenated OPFRs came mostly from effluents of WWTPs in economic/industrial zones. Thirteen samples of seawater were collected from...

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Veröffentlicht in:Marine pollution bulletin 2014-09, Vol.86 (1-2), p.569-574
Hauptverfasser: Hu, Mengyang, Li, Jun, Zhang, Beibei, Cui, Qinglan, Wei, Si, Yu, Hongxia
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container_issue 1-2
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container_title Marine pollution bulletin
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creator Hu, Mengyang
Li, Jun
Zhang, Beibei
Cui, Qinglan
Wei, Si
Yu, Hongxia
description •We discussed halogenated OPFRs in seawater from the Yellow and East China Seas.•The Yellow Sea area around Lianyungang was more heavily polluted than East China Sea.•Halogenated OPFRs came mostly from effluents of WWTPs in economic/industrial zones. Thirteen samples of seawater were collected from Yellow Sea and East China Sea near Qingdao, Lianyungang, and Xiamen, China. They were analyzed for halogenated organophosphorus flame retardants (OPFRs). The compounds selected for detection were Tris(2-chloroethyl) phosphate (TCEP), Tris(2-chloroisopropyl) phosphate (TCPP), Tris (1,3-dichloro-2-propyl) phosphate (TDCPP), and Tris(2,3-dibromopropyl) phosphate (TDBPP). The total concentrations ranged from 91.87 to 1392ng/L and the mean concentrations of these four chemicals were 134.44, 84.12, 109.28, and 96.70ng/L, respectively. TCEP exhibited the highest concentrations, although concentrations of TCPP and TDCPP were also fairly high in Lianyungang and Xiamen. Generally, Lianyungang was the most heavily polluted district, with very high concentrations of TCEP at LYG-2 (550.54ng/L) and LYG-4 (617.92ng/L). The main sources of halogenated OPFRs were municipal and industrial effluents of wastewater treatment plants in the nearby economic and industrial zones.
doi_str_mv 10.1016/j.marpolbul.2014.06.009
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Thirteen samples of seawater were collected from Yellow Sea and East China Sea near Qingdao, Lianyungang, and Xiamen, China. They were analyzed for halogenated organophosphorus flame retardants (OPFRs). The compounds selected for detection were Tris(2-chloroethyl) phosphate (TCEP), Tris(2-chloroisopropyl) phosphate (TCPP), Tris (1,3-dichloro-2-propyl) phosphate (TDCPP), and Tris(2,3-dibromopropyl) phosphate (TDBPP). The total concentrations ranged from 91.87 to 1392ng/L and the mean concentrations of these four chemicals were 134.44, 84.12, 109.28, and 96.70ng/L, respectively. TCEP exhibited the highest concentrations, although concentrations of TCPP and TDCPP were also fairly high in Lianyungang and Xiamen. Generally, Lianyungang was the most heavily polluted district, with very high concentrations of TCEP at LYG-2 (550.54ng/L) and LYG-4 (617.92ng/L). 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Psychology ; Halogenated ; Halogenated organophosphates ; Marine ; Marine and brackish environment ; Organophosphates ; Organophosphates - analysis ; Organophosphorus Compounds - analysis ; Phosphates ; Phosphines - analysis ; Regional distribution ; Sea water ; Sea water ecosystems ; Seawater ; Seawater - analysis ; Synecology ; Wastewater ; Water Pollutants, Chemical - analysis</subject><ispartof>Marine pollution bulletin, 2014-09, Vol.86 (1-2), p.569-574</ispartof><rights>2014 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2014 Elsevier Ltd. 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subjects Animal and plant ecology
Animal, plant and microbial ecology
Applied ecology
Biological and medical sciences
China
Cities
Economics
Ecotoxicology, biological effects of pollution
Effluents
Flame retardants
Flame Retardants - analysis
Fundamental and applied biological sciences. Psychology
Halogenated
Halogenated organophosphates
Marine
Marine and brackish environment
Organophosphates
Organophosphates - analysis
Organophosphorus Compounds - analysis
Phosphates
Phosphines - analysis
Regional distribution
Sea water
Sea water ecosystems
Seawater
Seawater - analysis
Synecology
Wastewater
Water Pollutants, Chemical - analysis
title Regional distribution of halogenated organophosphate flame retardants in seawater samples from three coastal cities in China
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