A new route towards multisulfur TTF-based components for organic metals

A new [2+4] cycloaddition reaction of oligomeric 1,3-dithiole-2,4,5-trithione and tetrathiafulvalene (TTF) derivatives leads to the formation of cycloadducts, which subsequent reactions give rise to hybride compounds consisting of 1,3-dithiole-2-thione unit and TTF unit connected together via one or...

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Veröffentlicht in:Synthetic metals 1993-03, Vol.56 (1), p.1931-1935
Hauptverfasser: Khodorkovsky, V.Y., Becker, J.Y., Bernstein, J.
Format: Artikel
Sprache:eng
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Zusammenfassung:A new [2+4] cycloaddition reaction of oligomeric 1,3-dithiole-2,4,5-trithione and tetrathiafulvalene (TTF) derivatives leads to the formation of cycloadducts, which subsequent reactions give rise to hybride compounds consisting of 1,3-dithiole-2-thione unit and TTF unit connected together via one or two sulfur atoms. Further chemical transformations of these new compounds are discussed.
ISSN:0379-6779
1879-3290
DOI:10.1016/0379-6779(93)90350-6