Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters

Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters

Two windmill-like Ag3Cu5 alkynyl clusters were synthesized and characterized. They display novel PL and ECL properties, which could be modified by changing the substituent on the alkynyl ligands. According to the study of electrochemical behaviours, ECL behaviours and ECL emission spectra of the Ag3...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-03, Vol.44 (9), p.3941-3944
Hauptverfasser: Jiang, Yi, Guo, Wen-Jing, Kong, De-Xian, Wang, Yong-Tao, Wang, Jin-Yun, Wei, Qiao-Hua
Format: Artikel
Sprache:eng
Schlagworte:
Copper - chemistry
Electrochemistry
Ligands
Luminescence
Organometallic Compounds - chemistry
Photochemical Processes
Pyridines - chemistry
Silver - chemistry
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Zusammenfassung:Two windmill-like Ag3Cu5 alkynyl clusters were synthesized and characterized. They display novel PL and ECL properties, which could be modified by changing the substituent on the alkynyl ligands. According to the study of electrochemical behaviours, ECL behaviours and ECL emission spectra of the Ag3Cu5 clusters, a possible ECL mechanism was proposed.
ISSN:1477-9234
DOI:10.1039/c4dt03369h