Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study

The solid state structure of Be[N(SiMe3)2]2 (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be-N bond is predominantly ionic, but some evidence for the presence of a partial Be-N double bond character was found.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (18), p.3889-3891
Hauptverfasser:	Naglav, D, Neumann, A, Bläser, D, Wölper, C, Haack, R, Jansen, G, Schulz, S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The solid state structure of Be[N(SiMe3)2]2 (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be-N bond is predominantly ionic, but some evidence for the presence of a partial Be-N double bond character was found.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c4cc09732g