Indium-catalyzed, novel route to β,β-disubstituted indanones via tandem Nakamura addition-hydroarylation-decarboxylation sequence

A novel method for the construction of β,β-disubstituted indanones has been developed via tandem Nakamura addition-hydroarylation-decarboxylation process. Indium(III) triflate was demonstrated as a versatile multitasking catalyst, which catalyzes three different chemical transformations under one-po...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (16), p.3347-3350
Hauptverfasser:	Rajesh, Nimmakuri, Prajapati, Dipak
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemistry Catalysis Cyclization Decarboxylation Indans - chemistry Indium - chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A novel method for the construction of β,β-disubstituted indanones has been developed via tandem Nakamura addition-hydroarylation-decarboxylation process. Indium(III) triflate was demonstrated as a versatile multitasking catalyst, which catalyzes three different chemical transformations under one-pot conditions.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c4cc09799h