Poly(3,4-dinitrothiophene)/SWCNT composite as a low overpotential hydrogen evolution metal-free catalyst

A novel metal-free hydrogen evolution reaction catalyst made of poly(3,4-dinitrothiophene)/SWCNT was developed. This catalyst presents a good hydrogen evolution reaction activity with a lower overpotential than metallic catalysts. Its performance was optimized to an overpotential of ca.0.040 V and a...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (1), p.78-82
Hauptverfasser: Xie, Ke, Wu, Haiping, Meng, Yuena, Lu, Kun, Wei, Zhixiang, Zhang, Zhong
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel metal-free hydrogen evolution reaction catalyst made of poly(3,4-dinitrothiophene)/SWCNT was developed. This catalyst presents a good hydrogen evolution reaction activity with a lower overpotential than metallic catalysts. Its performance was optimized to an overpotential of ca.0.040 V and a hydrogen generation rate of 44.2 mu mol h super(-1) cm super(-2).
ISSN:2050-7488
2050-7496
DOI:10.1039/c4ta04671d