Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light
A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)2Cl2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid lig...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (13), p.2645-2648 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)2Cl2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid ligand and platform for the assembly of a complicated catalytic system. |
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ISSN: | 1364-548X |
DOI: | 10.1039/c4cc09797a |