Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light

A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)2Cl2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid lig...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (13), p.2645-2648
Hauptverfasser: Sun, Dengrong, Gao, Yanhong, Fu, Jinlong, Zeng, Xianchong, Chen, Zhongning, Li, Zhaohui
Format: Artikel
Sprache:eng
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Zusammenfassung:A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)2Cl2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid ligand and platform for the assembly of a complicated catalytic system.
ISSN:1364-548X
DOI:10.1039/c4cc09797a