Beyond the Balz–Schiemann Reaction: The Utility of Tetrafluoroborates and Boron Trifluoride as Nucleophilic Fluoride Sources

The uses of tetrafluoroborates and boron trifluoride as fluoride sources in the Balz-Scheimann reaction are examined. Topics discussed include nucleophilic fluorinating agents and fluorinations of strained rings.

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Veröffentlicht in:Chemical reviews 2015-01, Vol.115 (2), p.566-611
Hauptverfasser: Cresswell, Alexander J., Davies, Stephen G., Roberts, Paul M., Thomson, James E.
Format: Artikel
Sprache:eng
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Zusammenfassung:The uses of tetrafluoroborates and boron trifluoride as fluoride sources in the Balz-Scheimann reaction are examined. Topics discussed include nucleophilic fluorinating agents and fluorinations of strained rings.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr5001805