Studies towards the synthesis of bielschowskysin. Construction of the highly functionalized bicyclo[3.2.0]heptane segment
A stereocontrolled approach for the construction of a highly functionalized bicyclo[3.2.0]heptane derivative embodying the bridged lactone present in the diterpene bielschowskysin is reported. The key step involves a stereoselective Cu(I)-catalyzed [2 + 2] photocycloaddition of a 1,6-diene embedded...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2015-02, Vol.13 (6), p.1846-1859 |
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| container_end_page | 1859 |
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| container_issue | 6 |
| container_start_page | 1846 |
| container_title | Organic & biomolecular chemistry |
| container_volume | 13 |
| creator | Jana, Anupam Mondal, Sujit Ghosh, Subrata |
| description | A stereocontrolled approach for the construction of a highly functionalized bicyclo[3.2.0]heptane derivative embodying the bridged lactone present in the diterpene bielschowskysin is reported. The key step involves a stereoselective Cu(I)-catalyzed [2 + 2] photocycloaddition of a 1,6-diene embedded in a sugar derivative. |
| doi_str_mv | 10.1039/c4ob02182g |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1477-0520 |
| ispartof | Organic & biomolecular chemistry, 2015-02, Vol.13 (6), p.1846-1859 |
| issn | 1477-0520 1477-0539 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1652418440 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bridged Bicyclo Compounds - chemistry Diterpenes - chemical synthesis Diterpenes - chemistry Heptanes - chemistry Molecular Conformation Stereoisomerism |
| title | Studies towards the synthesis of bielschowskysin. Construction of the highly functionalized bicyclo[3.2.0]heptane segment |
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