Topological ring-currents and bond-currents in the altan-[r,s]-coronenes

π-Electron ring-currents for the altans of the four regular [ r , s ]-coronenes are calculated by the topological HLPM approach. The bond-current pattern of the parent structure is generally preserved in the core of the corresponding altan . Altan -[10,5]-coronene appears to support an anomalous dia...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (1), p.1819-1822
Hauptverfasser: Dickens, T. K, Mallion, R. B
Format: Artikel
Sprache:eng
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Zusammenfassung:π-Electron ring-currents for the altans of the four regular [ r , s ]-coronenes are calculated by the topological HLPM approach. The bond-current pattern of the parent structure is generally preserved in the core of the corresponding altan . Altan -[10,5]-coronene appears to support an anomalous diamagnetic current in its [4 n ]-periphery. This invites further investigation. π-Electron ring-currents for the altans of the four regular [ r , s ]-coronenes are calculated by the topological HLPM approach.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc07322c