Analytical method for studying terahertz vibrations in a stearic acid single crystal

•We measured polarized terahertz absorption spectra of a stearic acid single crystal.•Several peaks were observed and angular dependences of intensity were analyzed.•Directions of THz vibrations were estimated. The anisotropy of terahertz absorption was investigated for a B-form single crystal of st...

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Veröffentlicht in:Infrared physics & technology 2014-11, Vol.67, p.427-431
Hauptverfasser: Tanno, Takenori, Arnold, Stevanus, Asari, Junya, Yodokawa, Shinichi, Kurabayashi, Toru
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Sprache:eng
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Zusammenfassung:•We measured polarized terahertz absorption spectra of a stearic acid single crystal.•Several peaks were observed and angular dependences of intensity were analyzed.•Directions of THz vibrations were estimated. The anisotropy of terahertz absorption was investigated for a B-form single crystal of stearic acid. A polarized terahertz spectrometer was used to obtain absorption spectra over the range of 1–5THz. Seven vibrational modes were observed; four exhibited significant angular dependence. Additionally, we demonstrated a simple approach for estimating the angle of the dipole moment for each vibrational mode.
ISSN:1350-4495
1879-0275
DOI:10.1016/j.infrared.2014.09.002