Functionality of graphene as a result of its heterogenic growth on SiC nanoparticles on the basis of reversible hydrogen storage

This article presents the results from research related to graphene functionality based on the production of spatial structures provided for the reversible storage of hydrogen. The functionality process was conducted during graphene synthesis onto a liquid metallic support, on a single level, using...

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Veröffentlicht in:International journal of hydrogen energy 2014-11, Vol.39 (34), p.19662-19671
Hauptverfasser: KULA, Piotr, KACZMAREK, Lukasz, ZAWADZKI, Piotr, KOLODZIEJCZYK, Lukasz, SZYMANSKI, Witold, NIEDZIELSKI, Piotr, PIETRASIK, Robert, DYBOWSKI, Konrad, KAZIMIERSKI, Dariusz, NOWAK, Dorota
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Sprache:eng
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Zusammenfassung:This article presents the results from research related to graphene functionality based on the production of spatial structures provided for the reversible storage of hydrogen. The functionality process was conducted during graphene synthesis onto a liquid metallic support, on a single level, using SiC nanoparticles. Within the scope of research it was proved that heterogenic growth of the domains of polycrystalline graphene onto the SiC nanoparticles is possible. These nanoparticles are in-built into the graphene structure constituting the pillars of the spatial structure. Material produced in such a way constitutes the foundation for creating a spatial 3D structure (through the rolling operation), called GraphRoll, for the reversible storage of hydrogen in order to conduct its sorption and de-sorption. So, independently of the theoretical configuration, deviations or a possible exception from the 2D configuration on the silicon carbide/graphene were discussed. These differences resulted from the difference between the crystallographic structures of the analyzed forms as well as the structure determined to decrease tensions within the structure.
ISSN:0360-3199
1879-3487
DOI:10.1016/j.ijhydene.2014.09.157