Co[at]NH sub(2)-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H sub(2) production

Co[at]NH sub(2)-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H sub(2) production

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH sub(2)-MIL-125(Ti)). The resulting hybrid system Co[at]MOF is demonstrated to be a robust heterogeneous composit...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Energy & environmental science 2014-12, Vol.8 (1), p.364-375
Hauptverfasser: Nasalevich, MA, Becker, R, Ramos-Fernandez, E V, Castellanos, S, Veber, S L, Fedin, M V, Kapteijn, F, Reek, JNH, van der Vlugt, JI, Gascon, J
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Composite materials
Derivatives
Encapsulation
Hybrid systems
Hydrogen evolution
Illumination
Metal-organic frameworks
Strategy
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH sub(2)-MIL-125(Ti)). The resulting hybrid system Co[at]MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co[at]MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.
ISSN:1754-5692
1754-5706
DOI:10.1039/c4ee02853h