Raman and structural comparison between the new gemstone pezzottaite Cs(Be sub(2)Li)Al sub(2)Si sub(6)O sub(18) and Cs-beryl

The Raman spectrum over the extended region 100-3800cm super(-1) of the new gemstone pezzottaite [ideal composition Cs(Be sub(2)Li)Al sub(2)Si sub(6)O sub(18)] from the type locality in Ambatovita (central Madagascar) is reported and compared with that of Cs-beryl from the Elba Island (San Piero in Campo). The extended Raman spectrum of pezzottaite has never been so far reported, and its vibrational features are described here in detail for the first time. The Raman spectrum of pezzottaite is characterized by two intense peaks at 111 and 1100cm super(-1), not present in the beryl spectrum, which allows a rapid identification of the stone. Moreover, in pezzottaite, two weak bands ascribable to the fundamental H sub(2)O stretching vibrations (i.e. 3591 and 3545cm super(-1)) are observed, despite that the mineral is nominally anhydrous, whereas beryl exhibits a single intense band at 3604cm super(-1). In order to complete the spectroscopic study, electron microprobe analysis in wavelength dispersive mode, laser ablation inductively coupled plasma mass spectrometry, and single-crystal X-ray diffraction characterization were performed on the two samples. The major and trace elements confirmed the higher amount of alkali in pezzottaite. Furthermore, pezzottaite exhibits a trigonal symmetry (R[Formulaomitted]c) caused by an ordered Li/Be distribution at the tetrahedral sites, while Cs-beryl has a hexagonal symmetry (P6/mcc) with a disordered Li/Be distribution. Copyright copyright 2014 John Wiley & Sons, Ltd. The Raman spectrum over the region 100-3800cm super(-1) of the new gemstone pezzottaite [Cs(Be sub(2)Li)Al sub(2)Si sub(6)O sub(18)] is compared with that of Cs-beryl. The spectrum of pezzottaite shows two main characteristic bands at 111 and 1100cm super(-1) with respect to Cs-beryl. The nature of the two bands is not completely understood, but Raman spectroscopy enables a quick identification of pezzottaite in gemology.