An Electrochemical Study of Sb/Acetylene Black Composite as Anode for Sodium-Ion Batteries

Sb/acetylene black (Sb/AB) composite was firstly applied as anode for sodium-ion batteries (SIBs). A great electrochemical performance of the composite was obtained when utilizing this composite for SIBs. It was found that the charge capacity can reach 473 mAh g super(-1) in the 70th cycle at a curr...

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Veröffentlicht in:Electrochimica acta 2014-11, Vol.146, p.328-334
Hauptverfasser: Hou, Hongshuai, Yang, Yingchang, Zhu, Yirong, Jing, Mingjun, Pan, Chengchi, Fang, Laibing, Song, Weixin, Yang, Xuming, Ji, Xiaobo
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Sprache:eng
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Zusammenfassung:Sb/acetylene black (Sb/AB) composite was firstly applied as anode for sodium-ion batteries (SIBs). A great electrochemical performance of the composite was obtained when utilizing this composite for SIBs. It was found that the charge capacity can reach 473 mAh g super(-1) in the 70th cycle at a current density of 100 mA g super(-1), and we also note that the capacity contributed by Sb was about 624 mAh g super(-1), which is very close to its theoretical sodium storage capacity (660 mAh g super(-1) corresponding to a formula of Na sub(3)Sb), demonstrating the full utilization of Sb. It is interesting to see that even at a high current density of 1600 mA g super(-1), the capacity can still reach 281 mAh g super(-1).
ISSN:0013-4686
DOI:10.1016/j.electacta.2014.09.080