Modeling of nonlinear viscoelasticity-viscoplasticity of bio-based polymer composites

Two different types of biodegradable polymers and polymer composites, namely Ecovio super( registered ) reinforced by 30 wt% wood-flour, and flax/starch composites prepared elsewhere, were analyzed experimentally and theoretically. The monotonic loading, stress-relaxation and creep-recovery experiments revealed a highly nonlinear viscoelastic/viscoplastic response. This behavior was treated by a three-dimensional constitutive model, analytically presented in a previous work. The model presumes that the materials follow a nonlinear viscoelastic path, while later on viscoplasticity prevails. The combination of the transient network model, related to the viscoelasticity, with a plasticity theory, lead to a constitutive model, which was proved to be capable of describing the experimental data of stress-relaxation, monotonic loading and creep-recovery in a unified manner. Deviations, which were detected for the first material types, requiring new parameter values, were attributed to structural changes arising from creep-recovery experiment.