Synthesis of 1,3,5,7-tetrakis(4-cyanatophenyl)adamantane and its microporous polycyanurate network for adsorption of organic vapors, hydrogen and carbon dioxide

Synthesis of 1,3,5,7-tetrakis(4-cyanatophenyl)adamantane and its microporous polycyanurate network for adsorption of organic vapors, hydrogen and carbon dioxide

This report presents the synthesis of a tetraphenyladamantane-based microporous polycyanurate network with a BET surface area of 843 m(2) g(-1) and a pore size of 7.8 Å. It uptakes 98.0 wt% benzene (298 K, P/P0 = 0.9), 1.49 wt% H2 (77 K/1 bar) and 12.8 wt% CO2 (273 K/1 bar) with CO2/N2 selectivity o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (76), p.11238-11241
Hauptverfasser: Shen, Changjiang, Yu, Hao, Wang, Zhonggang
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Networks
Polycyanurates
Porosity
Surface area
Surface chemistry
Synthesis
Uptakes
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Zusammenfassung:This report presents the synthesis of a tetraphenyladamantane-based microporous polycyanurate network with a BET surface area of 843 m(2) g(-1) and a pore size of 7.8 Å. It uptakes 98.0 wt% benzene (298 K, P/P0 = 0.9), 1.49 wt% H2 (77 K/1 bar) and 12.8 wt% CO2 (273 K/1 bar) with CO2/N2 selectivity of up to 112.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05021e