Molecular rearrangement of longifolene by Arthrobacter ilicis T sub(2)

Molecular rearrangement of longifolene by Arthrobacter ilicis T sub(2)

Arthrobacter ilicis T sub(2) brings about a unique type of cometabolic structural rearrangement of longifolene, a sesquiterpene, resulting in the formation of an acid. Infrared, nuclear magnetic resonance, mass spectrometry, and decoupling studies indicate that the acid product has a sativenelike st...

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Veröffentlicht in:Applied and environmental microbiology 1993-01, Vol.59 (5), p.1691-1693
Hauptverfasser: Bhosle, S, Kaliwal, S M, Paknikar, S K, Mavinkurve, S
Format: Artikel
Sprache:eng
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Zusammenfassung:Arthrobacter ilicis T sub(2) brings about a unique type of cometabolic structural rearrangement of longifolene, a sesquiterpene, resulting in the formation of an acid. Infrared, nuclear magnetic resonance, mass spectrometry, and decoupling studies indicate that the acid product has a sativenelike structure, which is confirmed by conversion of the acid to its methyl ester and hydrocarbon.
ISSN:0099-2240