One-pot hydrothermal synthesis of Co(OH)2 nanoflakes on graphene sheets and their fast catalytic oxidation of phenol in liquid phase

[Display omitted] •Co(OH)2–reduced graphene oxide (rGO) was synthesized by a one-pot hydrothermal method.•Phenol degradation rate of Co(OH)2–rGO using peroxymonosulfate was faster than Co(OH)2.•Kinetics of phenol degradation on Co(OH)2–rGO follows a first-order model.•A mechanism for phenol degradat...

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Veröffentlicht in:Journal of colloid and interface science 2013-07, Vol.402, p.230-236
Hauptverfasser: Yao, Yunjin, Xu, Chuan, Miao, Shiding, Sun, Hongqi, Wang, Shaobin
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Sprache:eng
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Zusammenfassung:[Display omitted] •Co(OH)2–reduced graphene oxide (rGO) was synthesized by a one-pot hydrothermal method.•Phenol degradation rate of Co(OH)2–rGO using peroxymonosulfate was faster than Co(OH)2.•Kinetics of phenol degradation on Co(OH)2–rGO follows a first-order model.•A mechanism for phenol degradation was presented. A cobalt hydroxide (Co(OH)2) nanoflake-reduced graphene oxide (rGO) hybrid was synthesized by a one-pot hydrothermal method using glucose as a reducing agent for graphene oxide (GO) reduction. The structural and surface properties of the material were investigated by scanning and transmission electron microscopies, energy-dispersive X-ray spectrometry, powder X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis. Catalytic activities of GO, rGO, Co(OH)2 and Co(OH)2–rGO in aqueous phenol degradation using peroxymonosulfate as an oxidant were compared. A synergetic effect on the catalytic activity was found on the Co(OH)2–rGO hybrid. Although rGO has weak catalytic activity, Co(OH)2–rGO hybrid showed a higher catalytic activity than Co(OH)2. The phenol degradation on Co(OH)2–rGO was extremely fast and took around 10min for 100% phenol removal. The degradation was found to follow the first order kinetics and a mechanism for phenol degradation was presented.
ISSN:0021-9797
1095-7103
DOI:10.1016/j.jcis.2013.03.070