Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

A novel Ni-catalyzed regio­divergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.

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Veröffentlicht in:Journal of the American Chemical Society 2014-12, Vol.136 (51), p.17702-17705
Hauptverfasser: Moragas, Toni, Cornella, Josep, Martin, Ruben
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel Ni-catalyzed regio­divergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja509077a