A Tröger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

A Tröger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

A Tröger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(III) complex. The resultant TB-MOP-Ru showed good CO2 and H2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (7), p.1271-1274
Hauptverfasser: Yang, Zhen-Zhen, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Ji, Guipeng, Liu, Zhimin
Format: Artikel
Sprache:eng
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Zusammenfassung:A Tröger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(III) complex. The resultant TB-MOP-Ru showed good CO2 and H2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number up to 2254 at 40 °C.
ISSN:1364-548X
DOI:10.1039/c4cc08295h