Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π‑Nanosheet: A Potential Organic Two-Dimensional Topological Insulator

A bulk material comprising stacked nanosheets of nickel bis(dithiolene) complexes is investigated. The average oxidation number is −3/4 for each complex unit in the as-prepared sample; oxidation or reduction respectively can change this to 0 or −1. Refined electrical conductivity measurement, involv...

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Veröffentlicht in:	Journal of the American Chemical Society 2014-10, Vol.136 (41), p.14357-14360
Hauptverfasser:	Kambe, Tetsuya, Sakamoto, Ryota, Kusamoto, Tetsuro, Pal, Tigmansu, Fukui, Naoya, Hoshiko, Ken, Shimojima, Takahiro, Wang, Zhengfei, Hirahara, Toru, Ishizaka, Kyoko, Hasegawa, Shuji, Liu, Feng, Nishihara, Hiroshi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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