Zn10(Im)20·4DBF: an unprecedented 10-nodal zeolitic topology with a 10-MR channel and 10 crystallographically independent Zn atoms

Zn10(Im)20·4DBF: an unprecedented 10-nodal zeolitic topology with a 10-MR channel and 10 crystallographically independent Zn atoms

By using a large-size amide, dibutylformamide (DBF), as a structure directing agent, a new zeolitic imidazolate framework (ZIF) was synthesized. The ZIF Zn10(Im)20·4DBF has an unprecedented zeolitic topology and features 10 crystallographically independent Zn atoms, a 10-membered ring (MR) channel a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (6), p.1131-1134
Hauptverfasser: Shi, Qi, Kang, Xiaozhen, Shi, Fa-Nian, Dong, Jinxiang
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:By using a large-size amide, dibutylformamide (DBF), as a structure directing agent, a new zeolitic imidazolate framework (ZIF) was synthesized. The ZIF Zn10(Im)20·4DBF has an unprecedented zeolitic topology and features 10 crystallographically independent Zn atoms, a 10-membered ring (MR) channel and an unusual 4-connected 10-nodal net.
ISSN:1364-548X
DOI:10.1039/c4cc07105k