Methanol from CO2 by Organo-Cocatalysis: CO2 Capture and Hydrogenation in One Process Step
Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of th...
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Veröffentlicht in: | Environmental science & technology 2014-12, Vol.48 (24), p.14799-14804 |
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creator | Reller, Christian Pöge, Matthias Lißner, Andreas Mertens, Florian O. R. L |
description | Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing reagent. The process provides a means to significantly improve the energy efficiency of CO2 to methanol conversions. |
doi_str_mv | 10.1021/es503914d |
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R. L</creator><creatorcontrib>Reller, Christian ; Pöge, Matthias ; Lißner, Andreas ; Mertens, Florian O. R. L</creatorcontrib><description>Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing reagent. The process provides a means to significantly improve the energy efficiency of CO2 to methanol conversions.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es503914d</identifier><identifier>PMID: 25396743</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Carbon Dioxide - chemistry ; Catalysis ; Catalytic reactions ; Chemistry ; Ethanolamines - chemistry ; Exact sciences and technology ; General and physical chemistry ; Hot Temperature ; Hydrogenation ; Methanol - chemistry ; Theory of reactions, general kinetics. Catalysis. 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The process provides a means to significantly improve the energy efficiency of CO2 to methanol conversions.</description><subject>Carbon Dioxide - chemistry</subject><subject>Catalysis</subject><subject>Catalytic reactions</subject><subject>Chemistry</subject><subject>Ethanolamines - chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Hot Temperature</subject><subject>Hydrogenation</subject><subject>Methanol - chemistry</subject><subject>Theory of reactions, general kinetics. Catalysis. 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subjects | Carbon Dioxide - chemistry Catalysis Catalytic reactions Chemistry Ethanolamines - chemistry Exact sciences and technology General and physical chemistry Hot Temperature Hydrogenation Methanol - chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
title | Methanol from CO2 by Organo-Cocatalysis: CO2 Capture and Hydrogenation in One Process Step |
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