Methanol from CO2 by Organo-Cocatalysis: CO2 Capture and Hydrogenation in One Process Step
Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of th...
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Veröffentlicht in: | Environmental science & technology 2014-12, Vol.48 (24), p.14799-14804 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing reagent. The process provides a means to significantly improve the energy efficiency of CO2 to methanol conversions. |
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ISSN: | 0013-936X 1520-5851 |
DOI: | 10.1021/es503914d |