Methanol from CO2 by Organo-Cocatalysis: CO2 Capture and Hydrogenation in One Process Step

Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of th...

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Veröffentlicht in:Environmental science & technology 2014-12, Vol.48 (24), p.14799-14804
Hauptverfasser: Reller, Christian, Pöge, Matthias, Lißner, Andreas, Mertens, Florian O. R. L
Format: Artikel
Sprache:eng
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Zusammenfassung:Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing reagent. The process provides a means to significantly improve the energy efficiency of CO2 to methanol conversions.
ISSN:0013-936X
1520-5851
DOI:10.1021/es503914d