Porous cobalt-manganese oxide nanocubes derived from metal organic frameworks as a cathode catalyst for rechargeable Li-O2 batteries
The development of cathode catalysts with a porous structure is essential to design Li-O2 batteries with a high rate performance and good cycle stability. Herein, spinel-type porous cobalt-manganese oxide (Co-Mn-O) nanocubes derived from metal organic frameworks were employed as an electrocatalyst i...
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Veröffentlicht in: | Nanoscale 2015-01, Vol.7 (2), p.720-726 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The development of cathode catalysts with a porous structure is essential to design Li-O2 batteries with a high rate performance and good cycle stability. Herein, spinel-type porous cobalt-manganese oxide (Co-Mn-O) nanocubes derived from metal organic frameworks were employed as an electrocatalyst in a Li-O2 battery. The battery with the porous Co-Mn-O nanocubes electrode showed a low overpotential and enhanced capacity. The synergistic effects of large specific surface area, porous structure, and the high electrocatalytic activity of the porous Co-Mn-O nanocubes electrode endowed the Li-O2 battery with a good rate performance and excellent cycle stability up to 100 cycles. |
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ISSN: | 2040-3372 |
DOI: | 10.1039/c4nr05865h |