Synthesis of gem-Difluorinated Nitroso Compounds

Synthesis of gem-Difluorinated Nitroso Compounds

A method for the synthesis of gem-difluorinated nitroso compounds is described. The reaction involves interaction of organozinc reagents with (bromo­difluoro­methyl)­tri­methyl­silane followed by nitrosation of difluorinated organozinc species with an n-butyl nitrite/chloro­trimethyl­silane system....

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Veröffentlicht in:Journal of organic chemistry 2014-12, Vol.79 (23), p.11819-11823
Hauptverfasser: Smirnov, Vladimir O, Struchkova, Marina I, Arkhipov, Dmitry E, Korlyukov, Alexander A, Dilman, Alexander D
Format: Artikel
Sprache:eng
Schlagworte:
Hydrocarbons, Fluorinated - chemistry
Hydrogen-Ion Concentration
Indicators and Reagents - chemistry
Molecular Structure
Nitrites - chemistry
Nitrosation
Nitroso Compounds - chemical synthesis
Nitroso Compounds - chemistry
Trimethylsilyl Compounds - chemistry
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Beschreibung
Zusammenfassung:A method for the synthesis of gem-difluorinated nitroso compounds is described. The reaction involves interaction of organozinc reagents with (bromo­difluoro­methyl)­tri­methyl­silane followed by nitrosation of difluorinated organozinc species with an n-butyl nitrite/chloro­trimethyl­silane system.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo5023537