CoMoO4 Nanoparticles Anchored on Reduced Graphene Oxide Nanocomposites as Anodes for Long-Life Lithium-Ion Batteries

A self-assembled CoMoO4 nanoparticles/reduced graphene oxide (CoMoO4NP/rGO), was prepared by a hydrothermal method to grow 3–5 nm sized CoMoO4 particles on reduced graphene oxide sheets and used as an anode material for lithium-ion batteries. The specific capacity of CoMoO4NP/rGO anode can reach up...

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Veröffentlicht in:ACS applied materials & interfaces 2014-11, Vol.6 (22), p.20414-20422
Hauptverfasser: Yao, Jianyu, Gong, Yongji, Yang, Shubin, Xiao, Peng, Zhang, Yunhuai, Keyshar, Kunttal, Ye, Gonglan, Ozden, Sehmus, Vajtai, Robert, Ajayan, Pulickel M
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Sprache:eng
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Zusammenfassung:A self-assembled CoMoO4 nanoparticles/reduced graphene oxide (CoMoO4NP/rGO), was prepared by a hydrothermal method to grow 3–5 nm sized CoMoO4 particles on reduced graphene oxide sheets and used as an anode material for lithium-ion batteries. The specific capacity of CoMoO4NP/rGO anode can reach up to 920 mAh g–1 at a current rate of 74 mA g–1 in the voltage range between 3.0 and 0.001 V, which is close to the theoretical capacity of CoMoO4 (980 mAh g–1). The fabricated half cells also show good rate capability and impressive cycling stability with 8.7% capacity loss after 600 cycles under a high current density of 740 mA g–1. The superior electrochemical performance of the synthesized CoMoO4NP/rGO is attributed to the synergetic chemical coupling effects between the conductive graphene networks and the high lithium-ion storage capability of CoMoO4 nanoparticles.
ISSN:1944-8244
1944-8252
DOI:10.1021/am505983m