Variability in atmospheric particulates and meteorological effects on their mass concentrations over Delhi, India

Simultaneous and continuous measurements of PM2.5 and PM10 along with other co-existent pollutants viz., black carbon (BC), CO, NO and NOx were carried out over Delhi with high resolution (5min) datasets from 1st Sept. 2010 to 23rd Aug. 2012. Arithmetic mean mass concentrations of PM2.5 and PM10 were about 130±103 and 222±142μgm−3 respectively during the entire measurement period, which are considerably higher than the annual averages of PM2.5 and PM10, stipulated by the National and International standards. It was noticed that the fine mode particles (PM2.5) were higher than the coarse mode particles (PM10–2.5) during post-monsoon (~89%), winter (~69%) and monsoon (~64%) periods; however, PM10–2.5 was higher (~22%) than PM2.5 during summer. Arithmetic mean mass concentrations of BC, CO, NO and NOx were about 7±5μgm−3, 2±1ppm, 17±17ppb and 30±24ppb, respectively. In the present study, highest fraction of BC (~6%) in PM2.5 mass was in winter, whereas the lowest fraction (~4%) was in summer. Relationships among PMs (particulate matters) and other pollutants indicated that the fine mode particles are highly correlated with BC (0.74) and CO (0.51). The effects of meteorological parameters on aerosols have been studied and a significant negative relationship (−0.45) between mixing height (MH) and PM2.5 has been noticed. Higher correlation was during winter (−0.55), however lower was in summer (−0.16). Relation between visibility (VIS) and PM2.5 was higher during post-monsoon (−0.85) and winter (−0.78) when the visibility was around 2km; however, it was relatively less correlated when VIS was greater than 2km during summer and monsoon. Relationship between PM2.5 and relative humidity (RH) showed a significant negative correlation (−0.56) for the entire study period. A positive correlation (0.32) was observed during the winter period with fine mode particles whereas negative correlation was seen with coarse mode particles during monsoon (−0.70) and summer (−0.51). •Long-term characterization of PM10 and PM2.5 along with other air pollutants was done over Delhi.•Coarse particles were higher (~22%) than fine particles during summer.•Fine particles were higher than coarse particles during the other seasons.•Fine particles are highly correlated with BC (0.80) and CO (0.53).