Boron-nitrogen analogues of the fluorenyl anion

Boron-nitrogen analogues of the fluorenyl anion

The synthesis and structural characterisation of [BPh(bipy)] and [BCl(bipy)] are described both of which contain a direduced bipy ligand (bipy = 2,2'-bipyridyl) and are analogues of the fluorenyl anion; DFT calculations highlight differences in the electronic structure of both species compared...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (21), p.5084-5086
Hauptverfasser: Mansell, Stephen M, Norman, Nicholas C, Russell, Christopher A
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis and structural characterisation of [BPh(bipy)] and [BCl(bipy)] are described both of which contain a direduced bipy ligand (bipy = 2,2'-bipyridyl) and are analogues of the fluorenyl anion; DFT calculations highlight differences in the electronic structure of both species compared to the fluorenyl anion.
ISSN:1477-9226
1477-9234
DOI:10.1039/c0dt00028k