Ring-Opening 1,3-Dichlorination of Donor–Acceptor Cyclopropanes by Iodobenzene Dichloride

Ring-Opening 1,3-Dichlorination of Donor–Acceptor Cyclopropanes by Iodobenzene Dichloride

Donor–acceptor cyclopropanes are reacted with iodobenzene dichloride to afford ring-opened products bearing chlorine atoms in the 1- and 3-positions, adjacent to the donor and acceptor groups. A variety of different donors (e.g., alkyl, aryl, N, and O) and acceptor moieties (e.g., ketones, diesters,...

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Veröffentlicht in:Organic letters 2014-11, Vol.16 (21), p.5804-5807
Hauptverfasser: Garve, Lennart K. B, Barkawitz, Philip, Jones, Peter G, Werz, Daniel B
Format: Artikel
Sprache:eng
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Zusammenfassung:Donor–acceptor cyclopropanes are reacted with iodobenzene dichloride to afford ring-opened products bearing chlorine atoms in the 1- and 3-positions, adjacent to the donor and acceptor groups. A variety of different donors (e.g., alkyl, aryl, N, and O) and acceptor moieties (e.g., ketones, diesters, and dinitriles) are used.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol5029139