Octadecanuclear Macrocycles and Nonanuclear Bowl-Shaped Structures Based on Two Analogous Pyridyl-Substituted Imidazole-4,5-dicarboxylate Ligands

Octadecanuclear Macrocycles and Nonanuclear Bowl-Shaped Structures Based on Two Analogous Pyridyl-Substituted Imidazole-4,5-dicarboxylate Ligands

Two types of unprecedented Cp*Rh-based (Cp* = η5-C5Me5) complexes, two octadeca­nuclear macrocycles, and a nona­nuclear bowl-shaped complex have been synthesized from two analogous pyridyl-functionalized imidazole-4,5-dicarboxylate ligands, 2-(pyridin-4-yl)-1H-imid­azole-4,5-dicarboxylate ligand and...

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Veröffentlicht in:Journal of the American Chemical Society 2014-11, Vol.136 (44), p.15521-15524
Hauptverfasser: Zhang, Ying-Ying, Shen, Xu-Yu, Weng, Lin-Hong, Jin, Guo-Xin
Format: Artikel
Sprache:eng
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Zusammenfassung:Two types of unprecedented Cp*Rh-based (Cp* = η5-C5Me5) complexes, two octadeca­nuclear macrocycles, and a nona­nuclear bowl-shaped complex have been synthesized from two analogous pyridyl-functionalized imidazole-4,5-dicarboxylate ligands, 2-(pyridin-4-yl)-1H-imid­azole-4,5-dicarboxylate ligand and 2-(pyridin-3-yl)-1H-imid­azole-4,5-dicarboxylate ligand, respectively.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja5096914