Star block-copolymers: enzyme-inspired catalysts for oxidation of alcohols in water

A number of fluorous amphiphilic star block-copolymers containing a tris(benzyltriazolylmethyl)amine motif have been prepared. These polymers assembled into well-defined nanostructures in water, and their mode of assembly could be controlled by changing the composition of the polymer. The polymers w...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-07, Vol.50 (58), p.7862-7865
Hauptverfasser:	Mugemana, Clément, Chen, Ba-Tian, Bukhryakov, Konstantin V, Rodionov, Valentin
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alcohols - chemistry Assembly Blocking Catalysis Catalysts Micelles Microscopy, Atomic Force Microscopy, Electron, Transmission Nanostructure Oxidation Oxidation-Reduction Polymers Polymers - chemical synthesis Water - analysis
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Beschreibung
Zusammenfassung:	A number of fluorous amphiphilic star block-copolymers containing a tris(benzyltriazolylmethyl)amine motif have been prepared. These polymers assembled into well-defined nanostructures in water, and their mode of assembly could be controlled by changing the composition of the polymer. The polymers were used for enzyme-inspired catalysis of alcohol oxidation.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c4cc03370a