Synthesis of some novel quinone diimine derivatives of benzo-15-crown-5 for application in Hg super(2+) recognition

A series of novel fluoroionophore bearing derivatives of benzo-15-crown-5 were synthesized by the amination of benzo-15-crown-5 followed by condensation with different quinones in the presence of titanium tetrachloride (TiCl sub(4)) and 1,4-diazabicyclo-[2.2.2]octane. The compounds were characterize...

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Veröffentlicht in:	Luminescence (Chichester, England) England), 2014-09, Vol.29 (6), p.586-590
Hauptverfasser:	Jagadale, S D, Sawant, AD, Patil, P P, Patil, DR, Mulik, A G, Chandam, DR, Sankpal, SA, Deshmukh, M B
Format:	Artikel
Sprache:	eng
Schlagworte:	Derivatives Infrared Luminescence Mass spectroscopy Quinones Recognition Spectra Tetrachlorides
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Zusammenfassung:	A series of novel fluoroionophore bearing derivatives of benzo-15-crown-5 were synthesized by the amination of benzo-15-crown-5 followed by condensation with different quinones in the presence of titanium tetrachloride (TiCl sub(4)) and 1,4-diazabicyclo-[2.2.2]octane. The compounds were characterized by infrared, super(1)H and super(13)C nuclear magnetic resonance, mass spectroscopy and elemental analysis. Absorption and fluorescence spectral characteristics of these compounds were studied. It was observed that the anthraquinone derivative was acting as an Hg super(2+) ion sensor. Copyright copyright 2013 John Wiley & Sons, Ltd.
ISSN:	1522-7235 1522-7243
DOI:	10.1002/bio.2585