Highly Sensitive Gas Sensor by the LaAlO sub(3)/SrTiO sub(3) Heterostructure with Pd Nanoparticle Surface Modulation

The palladium nanoparticle (Pd NP)-decorated LaAlO sub(3)/SrTiO sub(3) (LAO/STO) heterostructure is for the first time used as a hydrogen-gas sensor with very high sensitivity and workability at room temperature. The outstanding gas-sensing properties are due to the Pd NPs' catalytic effect to...

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Veröffentlicht in:Advanced materials (Weinheim) 2014-09, Vol.26 (34), p.5962-5968
Hauptverfasser: Chan, Ngai Yui, Zhao, Meng, Huang, JianXing, Au, Kit, Wong, Man Hon, Yao, Hei Man, Lu, Wei, Chen, Yan, Ong, Chung Wo, Chan, Helen Lai Wa, Dai, Jiyan
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Sprache:eng
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Zusammenfassung:The palladium nanoparticle (Pd NP)-decorated LaAlO sub(3)/SrTiO sub(3) (LAO/STO) heterostructure is for the first time used as a hydrogen-gas sensor with very high sensitivity and workability at room temperature. The outstanding gas-sensing properties are due to the Pd NPs' catalytic effect to different gases, resulting in charge coupling between the gas molecules and the two-dimensional electron gas (2DEG) through the Pd NPs by either a direct charge exchange or a change of the electron affinity. These results provide insight into the emerging properties at LAO/STO interfaces.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201401597