Versatile and sustainable alcoholysis of amides by a reusable CeO sub(2) catalyst

Versatile and sustainable alcoholysis of amides by a reusable CeO sub(2) catalyst

CeO sub(2) catalyzed the esterification between an equivalent molar ratio of primary amides and alcohols under neutral conditions, which provides the first versatile reusable catalytic system for direct alcoholysis of amides to esters with wider scope and 67 times higher turnover number (TON) than p...

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Veröffentlicht in:RSC advances 2014-08, Vol.4 (67), p.35803-35807
Hauptverfasser: Siddiki, SMAHakim, Touchy, Abeda Sultana, Tamura, Masazumi, Shimizu, Ken-ichi
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Amides
Catalysis
Catalysts
Equivalence
Esterification
Esters
Reusable
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Beschreibung
Zusammenfassung:CeO sub(2) catalyzed the esterification between an equivalent molar ratio of primary amides and alcohols under neutral conditions, which provides the first versatile reusable catalytic system for direct alcoholysis of amides to esters with wider scope and 67 times higher turnover number (TON) than previous catalytic systems.
ISSN:2046-2069
DOI:10.1039/c4ra07419j