A chiral BINOL-bridged imidazole dimer possessing sub-millisecond fast photochromism

We developed a chiral 1,1'-bi-2-naphthol-bridged imidazole dimer possessing 100 μs fast photochromism and high fatigue resistance. It offers great opportunities for the practical applications to fast photoresponsive chiral dopants, invisible security materials and optical trigger molecules to i...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (56), p.7481-7484
Hauptverfasser: Iwasaki, Takahiro, Kato, Tetsuya, Kobayashi, Yoichi, Abe, Jiro
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Sprache:eng
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Zusammenfassung:We developed a chiral 1,1'-bi-2-naphthol-bridged imidazole dimer possessing 100 μs fast photochromism and high fatigue resistance. It offers great opportunities for the practical applications to fast photoresponsive chiral dopants, invisible security materials and optical trigger molecules to induce the dynamic structural changes in biological matters.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02710h