The crystallographic observation of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts trapped in an irregular cavity

The crystallographic observation of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts trapped in an irregular cavity

We report two crystals and one gel formed by a chiral Mo(vi) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp super(3)-CH- pi interaction models of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adduc...

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Veröffentlicht in:CrystEngComm 2014-08, Vol.16 (37), p.8652-8655
Hauptverfasser: Chen, Yu, Ma, Li, Bian, Zheng, Jin, Rizhe, Kang, Chuanqing, Li, Zongjun, Gao, Xiang, Han, Fushe, Qiu, Xuepeng, Gao, Lianxun
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Adducts
Crystallography
Crystals
Holes
Inert
Solvents
Trapping
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container_issue 37
container_start_page 8652
container_title CrystEngComm
container_volume 16
creator Chen, Yu
Ma, Li
Bian, Zheng
Jin, Rizhe
Kang, Chuanqing
Li, Zongjun
Gao, Xiang
Han, Fushe
Qiu, Xuepeng
Gao, Lianxun
description We report two crystals and one gel formed by a chiral Mo(vi) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp super(3)-CH- pi interaction models of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts in an irregular accumulation environment are directly observed.
doi_str_mv 10.1039/c4ce01403k
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Adducts
Crystallography
Crystals
Holes
Inert
Solvents
Trapping
title The crystallographic observation of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts trapped in an irregular cavity
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