The crystallographic observation of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts trapped in an irregular cavity

We report two crystals and one gel formed by a chiral Mo(vi) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp super(3)-CH- pi interaction models of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adduc...

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Veröffentlicht in:CrystEngComm 2014-08, Vol.16 (37), p.8652-8655
Hauptverfasser: Chen, Yu, Ma, Li, Bian, Zheng, Jin, Rizhe, Kang, Chuanqing, Li, Zongjun, Gao, Xiang, Han, Fushe, Qiu, Xuepeng, Gao, Lianxun
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Sprache:eng
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Zusammenfassung:We report two crystals and one gel formed by a chiral Mo(vi) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp super(3)-CH- pi interaction models of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts in an irregular accumulation environment are directly observed.
ISSN:1466-8033
DOI:10.1039/c4ce01403k