The crystallographic observation of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts trapped in an irregular cavity
We report two crystals and one gel formed by a chiral Mo(vi) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp super(3)-CH- pi interaction models of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adduc...
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Veröffentlicht in: | CrystEngComm 2014-08, Vol.16 (37), p.8652-8655 |
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Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | We report two crystals and one gel formed by a chiral Mo(vi) complex. The particular accumulation of complex molecules creates inert irregular cavities for trapping a solvent adduct. The sp super(3)-CH- pi interaction models of mesitylene-mesitylene and mesitylene-CH sub(2)Cl sub(2)-mesitylene adducts in an irregular accumulation environment are directly observed. |
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ISSN: | 1466-8033 |
DOI: | 10.1039/c4ce01403k |