A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

The first Cu(i)-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H2)...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (62), p.8529-8532
Hauptverfasser: Zhou, An-Xi, Mao, Liu-Liang, Wang, Gang-Wei, Yang, Shang-Dong
Format: Artikel
Sprache:eng
Schlagworte:
Byproducts
Dehydrogenation
Hydrogen storage
Joining
Oxidants
Oxidizing agents
Synthesis
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Zusammenfassung:The first Cu(i)-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H2) as the only byproduct.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc01815j