Olefin formation in the oxidative deformylation of aldehydes by cytochrome P-450. Mechanistic implications for catalysis by oxygen-derived peroxide
We describe the cytochrome P-450 mediated oxidative deformylation of a xenobiotic aldehyde with introduction of unsaturation into the residual carbon framework.
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| Veröffentlicht in: | Journal of the American Chemical Society 1991-07, Vol.113 (15), p.5886-5887 |
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| container_end_page | 5887 |
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| container_issue | 15 |
| container_start_page | 5886 |
| container_title | Journal of the American Chemical Society |
| container_volume | 113 |
| creator | Vaz, Alfin D. N Roberts, Elizabeth A Coon, Minor J |
| description | We describe the cytochrome P-450 mediated oxidative deformylation of a xenobiotic aldehyde with introduction of unsaturation into the residual carbon framework. |
| doi_str_mv | 10.1021/ja00015a066 |
| format | Article |
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N</creatorcontrib><creatorcontrib>Roberts, Elizabeth A</creatorcontrib><creatorcontrib>Coon, Minor J</creatorcontrib><title>Olefin formation in the oxidative deformylation of aldehydes by cytochrome P-450. Mechanistic implications for catalysis by oxygen-derived peroxide</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>We describe the cytochrome P-450 mediated oxidative deformylation of a xenobiotic aldehyde with introduction of unsaturation into the residual carbon framework.</description><subject>aldehydes</subject><subject>Analytical, structural and metabolic biochemistry</subject><subject>Biological and medical sciences</subject><subject>Enzymes and enzyme inhibitors</subject><subject>Fundamental and applied biological sciences. 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| fulltext | fulltext |
| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 1991-07, Vol.113 (15), p.5886-5887 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_16157157 |
| source | American Chemical Society Journals |
| subjects | aldehydes Analytical, structural and metabolic biochemistry Biological and medical sciences Enzymes and enzyme inhibitors Fundamental and applied biological sciences. Psychology Oxidoreductases |
| title | Olefin formation in the oxidative deformylation of aldehydes by cytochrome P-450. Mechanistic implications for catalysis by oxygen-derived peroxide |
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