Fluorinated microporous organic polymers: design and applications in CO₂ adsorption and conversion

Fluorinated microporous organic polymers: design and applications in CO₂ adsorption and conversion

Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed hig...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-11, Vol.50 (90), p.13910-13913
Hauptverfasser: Yang, Zhen-Zhen, Zhao, Yanfei, Zhang, Hongye, Yu, Bo, Ma, Zhishuang, Ji, Guipeng, Liu, Zhimin
Format: Artikel
Sprache:eng
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Zusammenfassung:Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.
ISSN:1364-548X
DOI:10.1039/c4cc06423b