Electrochemical Mg super(2+) intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes

Electrochemical Mg super(2+) intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes

Mg super(2+) intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situX-ray diffraction evidenced the solid solution process of Mg super(2+) intercalation/deintercalation, while the super(57)Fe Mossbauer spectroscopy and X-ray absorption nea...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2013-10, Vol.1 (42), p.13055-13059
Hauptverfasser: Mizuno, Yoshifumi, Okubo, Masashi, Hosono, Eiji, Kudo, Tetsuichi, Oh-ishi, Katsuyoshi, Okazawa, Atsushi, Kojima, Norimichi, Kurono, Ryosuke, Nishimura, Shin-ichi, Yamada, Atsuo
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Sprache:eng
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Zusammenfassung:Mg super(2+) intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situX-ray diffraction evidenced the solid solution process of Mg super(2+) intercalation/deintercalation, while the super(57)Fe Mossbauer spectroscopy and X-ray absorption near edge structure revealed redox of both Cu and Fe.
ISSN:2050-7488
2050-7496
DOI:10.1039/c3ta13205f