Bis-ureidoquinoline as a Selective Fluoride Anion Sensor through Hydrogen-Bond Interactions
Bis-ureidoquinoline shows a characteristic UV–vis absorbance and turn-on fluorescence changes in the presence of the fluoride anion. Such selective changes probably originate from the hydrogen-bond interactions, as shown by the 1H NMR titration and DFT calculations. Bis-ureidoquinoline can be used a...
Gespeichert in:
Veröffentlicht in: | Journal of organic chemistry 2014-10, Vol.79 (19), p.9418-9422 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Bis-ureidoquinoline shows a characteristic UV–vis absorbance and turn-on fluorescence changes in the presence of the fluoride anion. Such selective changes probably originate from the hydrogen-bond interactions, as shown by the 1H NMR titration and DFT calculations. Bis-ureidoquinoline can be used as a fluoride-selective sensor for the detection of fluoride anions under illumination from a laboratory hand-held UV lamp. |
---|---|
ISSN: | 0022-3263 1520-6904 |
DOI: | 10.1021/jo501767g |