A bright entry to improve the performance of DSSCs with the influence of novel optoelectronic acridinedione based macromolecules in I super(-)/I sub(3) super(-) electrolytes

The performance of Ru(ii) dye-sensitized nanocrystalline TiO sub(2) solar cells (DSSCs) is described with newly synthesized multivalent macromolecules, containing excellent optoelectronic acridinedione linked with 1,2,3-triazole units, viaa novel and convenient Cu(I)-catalyzed alkyne and azide 1,3-dipolar cycloaddition (CuAAC) reaction. These unique macromolecules have proved to be highly suitable for utilizing additives in I super(-)/I sub(3) super(-) redox couple electrolytes. Among the various substitutions, the maximum photo-current conversion efficiency of about 6.4% with a V sub(oc) of 810 mV was obtained with electron rich substitutions in the nitrogen heteroatom.