4‘‘‘‘-Acetylsagittatin A, a Kaempferol Triglycoside from Kalanchoe streptantha

The methanolic extract from the leaves of Kalanchoe streptantha (Crassulaceae) afforded a new kaempferol 3-O-β-xylopyranosyl-(1→2)-α-rhamnopyranoside 7-O-(4‘‘‘‘-O-acetyl-α-rhamnopyranoside), named 4‘‘‘‘-acetylsagittatin A (1), and the known sagittatin A (2). The structures were determined by 1H-1H a...

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Veröffentlicht in:Journal of natural products (Washington, D.C.) D.C.), 1996, Vol.59 (3), p.327-329
Hauptverfasser: Costa, S. S, Jossang, A, Bodo, B
Format: Artikel
Sprache:eng
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Zusammenfassung:The methanolic extract from the leaves of Kalanchoe streptantha (Crassulaceae) afforded a new kaempferol 3-O-β-xylopyranosyl-(1→2)-α-rhamnopyranoside 7-O-(4‘‘‘‘-O-acetyl-α-rhamnopyranoside), named 4‘‘‘‘-acetylsagittatin A (1), and the known sagittatin A (2). The structures were determined by 1H-1H and 1H-13C COSY NMR and FAB mass spectroscopy and confirmed by analysis of the peracetylated derivative.
ISSN:0163-3864
1520-6025
DOI:10.1021/np960203u