Cellulose-supported N-heterocyclic carbene-palladium catalyst: Synthesis and its applications in the Suzuki cross-coupling reaction
•NHC ligand was introduced onto cellulose backbone to explore an avenue for polysaccharide-based catalysts.•Cellulose-supported NHC-Pd complex can efficiently promote Suzuki coupling reactions.•Catalysts can be recovered by easy filtration and can be used several times. A cellulose-supported N-methy...
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Veröffentlicht in: | Carbohydrate polymers 2014-12, Vol.114, p.476-483 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | •NHC ligand was introduced onto cellulose backbone to explore an avenue for polysaccharide-based catalysts.•Cellulose-supported NHC-Pd complex can efficiently promote Suzuki coupling reactions.•Catalysts can be recovered by easy filtration and can be used several times.
A cellulose-supported N-methylimidazole-palladium catalyst (Cell-NHC-Pd) was synthesized and used for Suzuki cross-coupling reactions between aryl halides and phenylboronic acids to create the corresponding coupling products in good to excellent yields. Moreover, the catalyst is easily recovered using only a few cycles of simple filtration. |
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ISSN: | 0144-8617 1879-1344 |
DOI: | 10.1016/j.carbpol.2014.08.030 |