Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu₄X₄ clusters as nodes

Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu₄X₄ clusters as nodes

Two novel cyclodiphosphazane cluster frameworks with Cu4X4 clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η(5)-C5H4)2(PN(t)Bu)2] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (82), p.12273-12276
Hauptverfasser: Siddiqui, Mujahuddin M, Mobin, Shaikh M, Senkovska, Irena, Kaskel, Stefan, Balakrishna, Maravanji S
Format: Artikel
Sprache:eng
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Zusammenfassung:Two novel cyclodiphosphazane cluster frameworks with Cu4X4 clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η(5)-C5H4)2(PN(t)Bu)2] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.
ISSN:1364-548X
DOI:10.1039/c4cc03810j