Direct validation of the restriction of intramolecular rotation hypothesis via the synthesis of novel ortho-methyl substituted tetraphenylethenes and their application in cell imaging
We demonstrate a novel synthetic approach to ortho-methyl substituted tetraphenylethene materials, which can be utilised for directly validating the restriction of intramolecular rotation hypothesis as the basic mechanism of aggregation-induced emission phenomenon and cell imaging.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (81), p.12058-12060 |
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| container_end_page | 12060 |
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| container_issue | 81 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 50 |
| creator | Zhang, Guo-Feng Chen, Ze-Qiang Aldred, Matthew P Hu, Zhe Chen, Tao Huang, Zhenli Meng, Xianggao Zhu, Ming-Qiang |
| description | We demonstrate a novel synthetic approach to ortho-methyl substituted tetraphenylethene materials, which can be utilised for directly validating the restriction of intramolecular rotation hypothesis as the basic mechanism of aggregation-induced emission phenomenon and cell imaging. |
| doi_str_mv | 10.1039/c4cc04241g |
| format | Article |
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2014-10, Vol.50 (81), p.12058-12060 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystallography, X-Ray Ethylenes - chemical synthesis Ethylenes - chemistry Ethylenes - metabolism Fluorescent Dyes - chemistry Fluorescent Dyes - metabolism HeLa Cells Humans Microscopy, Confocal Molecular Conformation |
| title | Direct validation of the restriction of intramolecular rotation hypothesis via the synthesis of novel ortho-methyl substituted tetraphenylethenes and their application in cell imaging |
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